First identified in 1872 in Sweden and studied in the U.S. beginning in the 1950s, acid rain is precipitation in the form of rain, snow, hail, dew, or fog that transports sulphur and nitrogen compounds from the high atmosphere to the ground. Sulphur dioxide (SO2) and nitrogen oxides (NO, NO2) are bi-products from burning fuels in electric utilities and from other industrial and natural sources. These chemicals react with water, oxygen, carbon dioxide, and sunlight in the atmosphere to form sulphuric and nitric acids. The acids reach the ground and change the chemistry within the environment.
Acid rain is linked to both natural and man-made sources. Nitrogen oxides are formed through the extreme heating of air when a thunderstorm produces lightning. Also, sulphurous gases are discharged from erupted volcanoes and rotting vegetation. Man-made sources of acid rain include the burning of any fuel that contains sulphur and nitrogen compounds, including public utilities, industrial broilers, motor vehicles, and chemical plants. Electric power generation accounted for 69 percent of total sulphur dioxide emissions in the U.S. in 2007 and 20 percent of nitrogen oxides, according to the U.S. Environmental Protection Agency (USEPA).
For detailed information on acid rain see here.